y shows an example of ligand-dependence of SCO behavior in Hofmann-like SCO compounds. Mössbauer study for the sample 1 indicates Fe(4-Clpy)2Ni(CN)4 does not have SCO behavior, while …
Fe(L) 2 [M(CN) 4] with L = 4-Ethyl Isonicotinate and M = Ni ...
May 23, 2024 · The resulting metal–organic frameworks (MOFs), Fe (L) 2 [M (CN) 4], show thermally induced spin crossover (SCO) in the 150–250 K temperature range. In these frameworks, the pillars …
Pressure Tunable Electronic Bistability in Fe (II) Hofmann ...
A comprehensive experimental and theoretical study of both thermal-induced spin transition (TIST) as a function of pressure and pressure-induced spin transition (PIST) at room temperature for the two …
Spin crossover in FeII cyanometallic frameworks
Jun 1, 2021 · Spin-crossover phenomenon in microcrystals and nanoparticles of a [Fe (2-mpz) 2 Ni (CN) 4] two-dimensional hofmann-type polymer: a detailed nano-topographic study
Is the surface of Hofmann-like spin-crossover {Fe (pz) [Pt (CN)
Jun 23, 2023 · Temperature dependent X-ray photoemission spectroscopy (XPS) has been employed to examine the spin-crossover (SCO) transition in the nanocrystals of 3D Hoffman-like {Fe (pz) [Pt (CN) …
Symmetry Breaking and Cooperative Spin Crossover in a Hofmann ...
Aug 1, 2023 · According to the magnetic and calorimetric data, both compounds undergo a strong cooperative spin transition featuring a 10–12 K wide hysteresis loop centered at 220 (Pt) and 211 K …
Tailoring zero-point energies in nanocrystalline 3D Hofmann ...
Apr 28, 2025 · Additionally, we synthesize the [Fe (pz)Pd (CN) 4] nanocrystals embedded in different polymeric matrices, including Poly (methyl methacrylate) (PMMA), Polyethylene glycol 6000 (PEG …